p-Aminoazobenzene , AR,98% , 60-09-3

Synonym(s):
4-Phenylazoaniline

CAS NO.：60-09-3

Empirical Formula: C12H11N3

Molecular Weight: 197.24

MDL number: MFCD00007854

EINECS: 200-453-6

PRODUCT Properties

• Melting point: 123-126 °C(lit.)
• Boiling point: >360 °C(lit.)
• Density: 1.2828 (rough estimate)
• refractive index: 1.6500 (estimate)
• storage temp.: 2-8°C
• solubility: Chloroform (Slightly), Methanol (Slightly)
• Colour Index: 11000
• pka: 2.82(at 25℃)
• color: Yellow crystals or orange needles with blue case from EtOH
• Water Solubility: 29.59mg/L(25 ºC)
• Merck: 14,419
• BRN: 1913042
• Stability: Stable. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: 60-09-3(CAS DataBase Reference)
• IARC: 2B (Vol. 8, Sup 7) 1987
• NIST Chemistry Reference: Benzenamine, 4-(phenylazo)-(60-09-3)
• EPA Substance Registry System: 4-Aminoazobenzene (60-09-3)

Description and Uses

This azoic coloring can be reduced in paraphenylenediamine (PPD). It ean be found in some semipermanent hair dyes, and patch tests are frequently positive (about 30%) in hairdressers with hand dermatitis. Because of cross-sensitivity, the detection of sensitization to p-aminoazobenzene may be assumed by a PPD test.

as a dye for lacquer, varnish, wax products, oi! stains and styrene res ins; in insecticides; used as an intermediate in the manufacture of Acid Yellow, diazo dyes and indulines.

Safety

• Symbol(GHS): GHS07,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H302-H317-H350-H410
• Precautionary statements: P202-P273-P280-P301+P312-P302+P352-P308+P313
• Hazard Codes: T,N,Xi
• Risk Statements: 45-50/53-36/37/38-20/21/22-46
• Safety Statements: 53-45-60-61-36/37/39-26-22
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 3
• RTECS: BY8225000
• HazardClass: IRRITANT
• PackingGroup: III
• HS Code: 29270000
• Hazardous Substances Data: 60-09-3(Hazardous Substances Data)
• Toxicity: LD50 intraperitoneal in mouse: 200mg/kg
• Limited Quantities: 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)