(+)-B-Chlorodiisopinocampheylborane , 60%inHeptane,ca.1.7mol/L , 112246-73-8

Synonym(s):
(+)-B-Chlorodiisopinocampheylborane;(+)-Ipc₂BCl

CAS NO.：112246-73-8

Empirical Formula: C20H34BCl

Molecular Weight: 320.75

MDL number: MFCD00074808

PRODUCT Properties

• Melting point: 53-55 °C(lit.)
• Boiling point: 369.6±25.0 °C(Predicted)
• Density: 0.91
• Flash point: >230 °F
• storage temp.: 2-8°C
• solubility: sol in both polar and nonpolar aprotic solvents like diethyl ether, THF, methylene chloride, pentane, hexane, etc
• form: clear liquid
• color: Colorless to Almost colorless
• InChI: InChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m0/s1
• InChIKey: PSEHHVRCDVOTID-YYNWCRCSSA-N
• SMILES: B(Cl)([C@H]1C[C@@]2([H])C[C@]([H])(C2(C)C)[C@@H]1C)[C@H]1C[C@@]2([H])C[C@]([H])(C2(C)C)[C@@H]1C
• CAS DataBase Reference: 112246-73-8(CAS DataBase Reference)

Description and Uses

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
• Hazard Codes: C
• Risk Statements: 34-37
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• F: 10-21
• HazardClass: 8
• PackingGroup: III
• HS Code: 29319090
• Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)