Iodotrimethylsilane , 97%, copper -containing stabilizer , 16029-98-4
Synonym(s):
TMIS;Trimethyliodosilane
CAS NO.：16029-98-4
Empirical Formula: C3H9ISi
Molecular Weight: 200.09
MDL number: MFCD00001028
EINECS: 240-171-0
| Pack Size | Price | Stock | Quantity |
| 5G | RMB24.00 | In Stock |
|
| 25G | RMB68.00 | In Stock |
|
| 100G | RMB204.00 | In Stock |
|
| 250g | RMB399.20 | In Stock |
|
| 1KG | RMB1519.20 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | <0°C |
| Boiling point: | 106 °C(lit.) |
| Density | 1.406 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | −25 °F |
| storage temp. | -20°C |
| solubility | reacts |
| form | Liquid |
| Specific Gravity | 1.47 |
| color | Clear colorless to reddish |
| Water Solubility | reacts |
| Sensitive | Moisture & Light Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 1731136 |
| Stability: | Moisture Sensitive (Reactive) |
| InChIKey | CSRZQMIRAZTJOY-UHFFFAOYSA-N |
| CAS DataBase Reference | 16029-98-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Iodotrimethylsilane(16029-98-4) |
| EPA Substance Registry System | Silane, iodotrimethyl- (16029-98-4) |
Description and Uses
Iodotrimethylsilane is used for the introduction of trimethylsilyl group in organic synthesis. It is also useful for gas chromatography analysis by converting alcohol into a silyl ether derivative, thereby making it more volatile than the original molecule.Iodotrimethylsilane is a highly efficient reagent for the cleavage of ethers, esters, carbamates, ketals, and lactones. It is also used for the introduction of TMS groups, such as TMS enol ethers, and is a key reagent for the selective removal of N-Cbz groups in the presence of a trimethyltin moiety.This reagent has recently been reported to convert allyl and benzyl phosphotriesters to the corresponding iodides.
Safety
| Symbol(GHS) |   GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H225-H314 |
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 |
| Hazard Codes | F,C |
| Risk Statements | 11-14-34 |
| Safety Statements | 16-26-36/37/39-43-45-25 |
| RIDADR | UN 2924 3/PG 2 |
| WGK Germany | 3 |
| F | 8-21 |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 29310095 |
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
