A5341412
Methyl acrylate , StandardforGC,≥99.5%(GC) , 96-33-3
Synonym(s):
Methyl acrylate;Methyl propenoate, Acrylic acid methyl ester
CAS NO.：96-33-3
Empirical Formula: C4H6O2
Molecular Weight: 86.09
MDL number: MFCD00008627
EINECS: 202-500-6
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -75 °C (lit.) |
| Boiling point: | 80 °C (lit.) |
| Density | 0.956 g/mL at 25 °C (lit.) |
| vapor density | 3 (vs air) |
| vapor pressure | 67.5 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | 26.6 °F |
| storage temp. | 2-8°C |
| solubility | 60g/l |
| form | Liquid |
| color | Clear |
| Odor | acrid odor |
| PH | 7 (20°C) |
| explosive limit | 2.8%(V) |
| Odor Threshold | 0.0035ppm |
| Water Solubility | 60 g/L (20 ºC) |
| Sensitive | Light Sensitive |
| Merck | 14,6011 |
| BRN | 605396 |
| Henry's Law Constant | (x 10-4 atm?m3/mol):
1.3 at 20 °C (approximate - calculated from water solubility and vapor pressure) |
| Exposure limits | TLV-TWA 10 ppm (～35 mg/m3) (ACGIH
and MSHA), TLV-TWA skin 10 ppm
(～35 mg/m3) (OSHA); IDLH 1000 ppm
(NIOSH). |
| Dielectric constant | 7.1200000000000001 |
| Stability: | Stable. Incompatible with bases, acids, oxidizing agents, peroxides. May polymerize on exposure to light. Highly flammable. Commercial product may be inhibited by the presence of hydroquinone monomethyl ether. |
| LogP | 0.739 at 25℃ |
| Surface tension | 26.96mN/m at 293.15K |
| CAS DataBase Reference | 96-33-3(CAS DataBase Reference) |
| IARC | 2B (Vol. 39, Sup 7, 71, 122) 2019 |
| NIST Chemistry Reference | 2-Propenoic acid, methyl ester(96-33-3) |
| EPA Substance Registry System | Methyl acrylate (96-33-3) |
| ECETOC JACC REPORT | Methyl acrylate (96-33-3) |
Description and Uses
Methyl acrylate is an organic compound with the formula CH2CHCO2CH3. It is the methyl ester of acrylic acid. It is a colourless liquid with a characteristic acrid odor. It is mainly produced to make acrylate fiber, which is used to weave synthetic carpets. It is also a reagent in the synthesis of various pharmaceutical intermediates.
Methyl acrylate is a monomer used in the manufacture of acrylic fibers, plastic films, textiles, papercoatings, and other acrylate ester resins. It is also used in amphoteric surfactants.
Safety
| Symbol(GHS) |   GHS02,GHS06 |
| Signal word | Danger |
| Hazard statements | H225-H302+H312-H315-H317-H319-H331-H335-H412 |
| Precautionary statements | P210-P273-P280-P301+P312-P303+P361+P353-P304+P340+P311 |
| Hazard Codes | F,Xn |
| Risk Statements | 11-20/21/22-36/37/38-43 |
| Safety Statements | 9-25-26-33-36/37-43-43A |
| RIDADR | UN 1919 3/PG 2 |
| OEB | A |
| OEL | TWA: 10 ppm (35 mg/m3) [skin] |
| WGK Germany | 2 |
| RTECS | AT2800000 |
| F | 8 |
| Autoignition Temperature | 874 °F |
| TSCA | Yes |
| HS Code | 2916 12 00 |
| HazardClass | 3 |
| PackingGroup | II |
| Hazardous Substances Data | 96-33-3(Hazardous Substances Data) |
| Toxicity | LD50 orally in rats: 0.3 g/kg (Smyth, Carpenter) |
| IDLA | 250 ppm |
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
