(R)-(+)-α-Methylbenzylamine , 99%,(98%ee) , 3886-69-9

Synonym(s):
(R)-(+)-1-Phenylethylamine;(R)-(+)-1-Phenylethylamine;D-α-Methylbenzylamine

CAS NO.：3886-69-9

Empirical Formula: C8H11N

Molecular Weight: 121.18

MDL number: MFCD00064405

EINECS: 223-423-4

PRODUCT Properties

• Melting point: -10 °C
• alpha: 40 º (neat)
• Boiling point: 187-189 °C(lit.)
• Density: 0.952 g/mL at 20 °C(lit.)
• vapor pressure: 0.5 mm Hg ( 20 °C)
• refractive index: n20/D 1.526(lit.)
• Flash point: 175 °F
• storage temp.: 2-8°C
• solubility: 40g/l
• form: Liquid
• pka: 9.04±0.10(Predicted)
• color: Clear colorless
• PH: >7 (40g/l, H2O, 20℃)
• optical activity: [α]23/D +38°, neat
• Water Solubility: 40 g/L (20 ºC)
• Sensitive: Air Sensitive
• Merck: 14,6026
• BRN: 2410916
• InChIKey: RQEUFEKYXDPUSK-SSDOTTSWSA-N
• LogP: 1.31-1.49 at 25℃
• CAS DataBase Reference: 3886-69-9(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, «alpha»-methyl-, (R)-(3886-69-9)
• EPA Substance Registry System: Benzenemethanamine, .alpha.-methyl-, (.alpha.R)- (3886-69-9)

Description and Uses

(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.

Safety

• Symbol(GHS): GHS05,GHS07
• Signal word: Danger
• Hazard statements: H302+H312-H314
• Precautionary statements: P270-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
• Hazard Codes: C
• Risk Statements: 21/22-34
• Safety Statements: 26-28-36/37/39-45-28A-27
• RIDADR: UN 2735 8/PG 2
• WGK Germany: 3
• F: 3-10-23-34
• Autoignition Temperature: 355 °C DIN 51794
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• HS Code: 29214980