4,4′-Methylene-bis(2-chloroaniline) , Analyze the standard products for environmental analysis , 101-14-4
Synonym(s):
2,2′-Dichloro-4,4′-methylenedianiline;4,4′-Diamino-3,3′-dichlorodiphenylmethane
CAS NO.：101-14-4
Empirical Formula: C13H12Cl2N2
Molecular Weight: 267.15
MDL number: MFCD00047829
EINECS: 202-918-9
PRODUCT Properties
| Melting point: | 102-107 °C(lit.) |
| Boiling point: | 202-214 °C0.3 mm Hg(lit.) |
| Density | 1.44 |
| vapor pressure | 0.001Pa at 20℃ |
| refractive index | 1.6710 (estimate) |
| Flash point: | >230 °F |
| solubility | Acetonitrile (Slightly), DMSO (Slightly), Methanol (Slightly) |
| form | solid |
| pka | 3.33±0.25(Predicted) |
| color | Light orange to Yellow to Green |
| Water Solubility | <0.1 g/100 mL at 25 ºC |
| Merck | 14,6059 |
| BRN | 1882318 |
| Stability: | Stable, but decomposes exothermically, and possibly explosively, above 200 C. Incompatible with strong oxidizing agents. |
| InChIKey | IBOFVQJTBBUKMU-UHFFFAOYSA-N |
| LogP | 2.5 at 25℃ |
| CAS DataBase Reference | 101-14-4(CAS DataBase Reference) |
| IARC | 1 (Vol. Sup 7, 57, 99, 100F) 2012 |
| NIST Chemistry Reference | Aniline), methylene bis-4,4'-(2-chloro-(101-14-4) |
| EPA Substance Registry System | 4,4'-Methylenebis(2-chloroaniline) (101-14-4) |
Description and Uses
4,4'-Methylene bis(2-chloroaniline) (or MBOCA) is a synthetic chemical used primarily to make polyurethane products. Pure MBOCA is a colorless, crystalline solid, but the commonly used form is usually yellow, tan, or brown pellets. It has no smell or taste. Examples of these products include gears, gaskets, sport boots, roller skate wheels, shoe soles, rolls and belt drives in cameras, computers and copy machines, wheels and pulleys for escalators and elevators, components in home appliances, and various military applications. It is also used as a coating in chemical reactions to "set" glues, plastics, and adhesives. Because plastics have many uses, MBOCA is widely used.
Curing agent for polyurethanes and epoxy resins
Safety
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H302-H341-H350-H410 |
| Precautionary statements | P201-P273-P301+P312+P330-P308+P313 |
| Hazard Codes | T,N |
| Risk Statements | 45-22-50/53-53-50-68 |
| Safety Statements | 53-45-60-61-36/37 |
| RIDADR | UN 3077 9/PG 3 |
| OEB | E |
| OEL | TWA: 0.003 mg/m3 [skin] |
| WGK Germany | 3 |
| RTECS | CY1050000 |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 29215900 |
| Hazardous Substances Data | 101-14-4(Hazardous Substances Data) |
| Toxicity | LD50 oral in rat: 1140mg/kg |
