A0565650
Ammoniumsulfidesolution , 20%-26%inH2O , 12135-76-1
CAS NO.：12135-76-1
Empirical Formula: H8N2S
Molecular Weight: 68.14
MDL number: MFCD00010892
EINECS: 235-223-4
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | decomposes [HAW93] |
| Boiling point: | 40 °C |
| Density | 1 g/mL at 25 °C |
| vapor pressure | 600 hPa at 20 °C |
| FEMA | 2053 | AMMONIUM SULFIDE |
| refractive index | n |
| Flash point: | 90 °F |
| storage temp. | room temp |
| solubility | Very soluble in water, almost insoluble in alcohol and oils. |
| pka | 3.42±0.70(Predicted) |
| form | Liquid |
| color | Yellow to orange |
| Specific Gravity | 1.2 |
| Odor | Ammonia odour |
| PH Range | 9.5 ( 45% aqueous solution) |
| PH | 9.5 (450g/L in H2O) |
| biological source | synthetic |
| Odor Type | sulfurous |
| explosive limit | 4-46% |
| Water Solubility | Miscible with water, alcohol and liquid ammonia. |
| Merck | 13,560 |
| Stability: | Stable. Pure material is highly flammable - note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, copper, brass, bronze, strong bases, zinc, aluminium. |
| InChIKey | UXXGWUQNRMPNKH-UHFFFAOYSA-N |
| CAS DataBase Reference | 12135-76-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ammonium sulfide (12135-76-1) |
Description and Uses
Ammonium sulfide solution is used occasionally in photographic developing, to apply patina to bronze, and in textile manufacturing. Ammonium sulfide is a very useful reagent in mineral analysis. Used in continuous culture of saccharomyces cerevisiae, useful in a double staining technique for visualization of astrocytes and microglia from brain sections and astroglial cell cultures. It plays an important role to modify the surface of low κ dielectric thin films. It is essential for molecular beam epitaxy regrowth. It is an unstable salt and acts as a selective reducing agent.
Safety
| Symbol(GHS) |   GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H226-H314 |
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 |
| Hazard Codes | C,N,F |
| Risk Statements | 11-31-34-50-10 |
| Safety Statements | 26-36/37/39-45-61-16 |
| RIDADR | UN 2683 8/PG 2 |
| WGK Germany | - |
| F | 10-13-23 |
| TSCA | Yes |
| HazardClass | 8 |
| PackingGroup | II |
| HS Code | 28309090 |
| Hazardous Substances Data | 12135-76-1(Hazardous Substances Data) |
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
