A0743312
(S)-(-)-2-Amino-2'-hydroxy-1,1'-binaphthyl , 98% , 137848-29-4
Synonym(s):
(S)-(−)-2-Amino-2′-hydroxy-1,1′-binaphthalene;(S)-NOBIN
| Pack Size | Price | Stock | Quantity |
| 100MG | RMB421.60 | In Stock |
|
| 500MG | RMB1684.80 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 171.0 to 175.0 °C |
| Boiling point: | 471.5±30.0 °C(Predicted) |
| Density | 1.275 |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| form | powder to crystal |
| pka | 8.90±0.50(Predicted) |
| color | White to Light red to Green |
| InChI | 1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2 |
| InChIKey | HIXQCPGXQVQHJP-UHFFFAOYSA-N |
| SMILES | Nc1c(c4c(cc1)cccc4)c2c3c(ccc2O)cccc3 |
| CAS DataBase Reference | 137848-29-4(CAS DataBase Reference) |
Description and Uses
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig?Buchwald arylation reaction.
Safety
| Symbol(GHS) |   GHS05,GHS09 |
| Signal word | Danger |
| Hazard statements | H318-H410 |
| Precautionary statements | P273-P280-P305+P351+P338-P501 |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi,N |
| Risk Statements | 36/37/38-50/53-41 |
| Safety Statements | 26-36/37/39-61-60-39 |
| RIDADR | UN 3077 9 / PGIII |
| WGK Germany | 3 |
| HS Code | 29222990 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Aquatic Acute 1 Aquatic Chronic 1 Eye Dam. 1 |
