Molybdenum(VI)tetrachlorideoxide , ≥97% , 13814-75-0

Synonym(s):
Molybdenum chloride oxide;Molybdenum oxide chloride;Molybdenum oxytetrachloride;Molybdenum tetrachloride monoxide;Molybdenum(VI) oxychloride

CAS NO.：13814-75-0

Empirical Formula: Cl4MoO

Molecular Weight: 253.75

MDL number: MFCD00014222

PRODUCT Properties

• Melting point: 100-101°C
• storage temp.: 2-8°C
• form: Powder
• color: green
• Sensitive: air sensitive, moisture sensitive, store cold
• InChI: InChI=1S/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4
• InChIKey: UYEGPKGLVUUIGD-UHFFFAOYSA-J
• SMILES: [Mo](Cl)(Cl)(Cl)(Cl)=O
• CAS DataBase Reference: 13814-75-0

Description and Uses

Molybdenum(VI) tetrachloride oxide can be used:

• To prepare a binary metal catalyst (MoOCl₄-n-BuLi) for the living polymerization of various acetylenes.
• As an oxidant in the aromatization of various Hantzsch-1,4-dihydropyridines.
• As a molybdenum (Mo) precursor to prepare nafion-Mo composite material, which is used as a catalyst for the preparation of nitrones by reacting primary amines with aldehydes.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
• PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
• Hazard Codes: Xi,C
• Risk Statements: 36/37/38-34
• Safety Statements: 26-37/39-45-36/37/39
• RIDADR: UN 3260 8/PG 3
• WGK Germany: 3
• HS Code: 2827499090
• Storage Class: 8A - Combustible corrosive hazardous materials
• Hazard Classifications: Skin Corr. 1B