Bromobenzene , 99.5% , 108-86-1
Synonym(s):
Bromobenzene;Phenyl bromide
CAS NO.：108-86-1
Empirical Formula: C6H5Br
Molecular Weight: 157.01
MDL number: MFCD00000055
EINECS: 203-623-8
PRODUCT Properties
| Melting point: | -31 °C |
| Boiling point: | 156 °C(lit.) |
| Density | 1.491 g/mL at 25 °C(lit.) |
| vapor density | 5.41 (vs air) |
| vapor pressure | 10 mm Hg ( 40 °C) |
| refractive index | n |
| Flash point: | 124 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene. |
| form | Liquid |
| color | Clear colorless to faintly yellow |
| Odor | pleasant smell |
| explosive limit | 0.5-2.5%(V) |
| Water Solubility | insoluble. <0.1 g/100 mL at 20.5 ºC |
| Merck | 14,1406 |
| BRN | 1236661 |
| Henry's Law Constant | 2.47 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997) |
| Dielectric constant | 5.4（20℃） |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChIKey | QARVLSVVCXYDNA-UHFFFAOYSA-N |
| LogP | 3.14 at 25℃ |
| Surface tension | 33.5mN/m at 303.15K |
| CAS DataBase Reference | 108-86-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, bromo-(108-86-1) |
| EPA Substance Registry System | Bromobenzene (108-86-1) |
Description and Uses
Bromobenzene is a flammable, clear, colorlessmobile liquid with a pleasant odor. Molecularweight=157.02. Specific gravity (H2O:1)=1.48; Boilingpoint=156℃; Freezing/Melting point=2 31℃; Flashpoint=51℃; Autoignition temperature=565℃. Explosivelimits in air: LEL=6%; UEL=36.5%[icsc]. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 2, Reactivity 0. Very slightly soluble in water; solubility=0.04% at 25℃.
Bromobenzene is an additive to motor oils and used as a crystallizing solvent. It is used as an ingredient in the manufacture of phencyclidine, a recreational drug.
Safety
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
| Signal word | Warning |
| Hazard statements | H226-H315-H411 |
| Precautionary statements | P210-P273-P302+P352 |
| Hazard Codes | Xi,N,F,T |
| Risk Statements | 10-38-51/53-39/23/24/25-23/24/25 |
| Safety Statements | 61-45-36/37 |
| RIDADR | UN 2514 3/PG 3 |
| WGK Germany | 2 |
| RTECS | CY9000000 |
| Autoignition Temperature | 565 °C |
| TSCA | Yes |
| HS Code | 2903 99 80 |
| HazardClass | 3 |
| PackingGroup | III |
| Hazardous Substances Data | 108-86-1(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 2383 mg/kg |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
