A1214612
tert-Butylamine , 99.5%, heavy distillation , 75-64-9
Synonym(s):
2-Amino-2-methylpropane;TBA;tert-Butylamine
CAS NO.：75-64-9
Empirical Formula: C4H11N
Molecular Weight: 73.14
MDL number: MFCD00008050
EINECS: 200-888-1
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -67 °C (lit.) |
| Boiling point: | 46 °C (lit.) |
| Density | 0.696 g/mL at 25 °C (lit.) |
| vapor density | 2.5 (vs air) |
| vapor pressure | 5.7 psi ( 20 °C) |
| refractive index | n |
| Flash point: | −36.4 °F |
| storage temp. | Store below +30°C. |
| solubility | water: miscible1000g/L at 25°C |
| pka | 10.68(at 25℃) |
| form | Liquid |
| color | Clear |
| PH | 12 (100g/l, H2O, 20℃) |
| Odor | Like ammonia. |
| Odor Threshold | 0.17ppm |
| explosive limit | 1.5-9.2%(V) |
| Water Solubility | MISCIBLE |
| Sensitive | Air Sensitive |
| Merck | 14,1545 |
| BRN | 605267 |
| Dielectric constant | 4.3099999999999996 |
| Stability: | Stable. Incompatible with strong acids, strong oxidizing agents. Highly flammable. |
| CAS DataBase Reference | 75-64-9(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Propanamine, 2-methyl-(75-64-9) |
| EPA Substance Registry System | tert-Butylamine (75-64-9) |
Description and Uses
tert-butylamine is used as a precursor for the preparation of rubber accelerators, pharmaceuticals and dyes. It is employed in synthesis of N-tert-butyl-acetamide, isoquinolines, pyridines, decumbenine, sulfontes, sulfonamides and methyl beta-ketophosphonate. It is also used in the study the effect of amines in influencing atmospheric sulfuric acid - water nucleation, hydroamination of terminal alkynes and measuring the surface acidity of solid catalyst. It acts as an indicator molecule in the study of NMR -based pH determination method.
Safety
| Symbol(GHS) |    GHS02,GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H225-H302-H314-H331-H412 |
| Precautionary statements | P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | F,C,T |
| Risk Statements | 11-20/22-35-25-20-52/53 |
| Safety Statements | 16-26-36/37/39-45-28A-61 |
| RIDADR | UN 3286 3/PG 2 |
| WGK Germany | 1 |
| RTECS | EO3330000 |
| F | 2-10 |
| Autoignition Temperature | 716 °F |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 29211980 |
| Hazardous Substances Data | 75-64-9(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 80 mg/kg |
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
