BMIMPF6 , 97% , 174501-64-5

Synonym(s):
BMIMPF₆

CAS NO.：174501-64-5

Empirical Formula: C8H15F6N2P

Molecular Weight: 284.18

MDL number: MFCD03093295

EINECS: 678-095-9

PRODUCT Properties

• Melting point: 6.5 °C
• Boiling point: >340°C
• Density: 1.38 g/mL at 20 °C (lit.)
• refractive index: n20/D 1.41
• Flash point: >350°C
• storage temp.: Store below +30°C.
• solubility: Acetone, Methanol
• form: Viscous Liquid
• Specific Gravity: 1.396
• color: Clear colorless to pale yellow
• PH: 5 (H2O, 20℃)
• Water Solubility: Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
• Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
• Merck: 14,1581
• InChIKey: IXQYBUDWDLYNMA-UHFFFAOYSA-N
• CAS DataBase Reference: 174501-64-5(CAS DataBase Reference)
• ECW: 4.2 V

Description and Uses

1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.

It can also be used as a medium for reactions such as:

• Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.
• Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.
• Lipase-catalyzed enantioselective acylation of allylic alcohols.
• Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319
• Precautionary statements: P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
• Hazard Codes: Xi,Xn
• Risk Statements: 36/37/38-22
• Safety Statements: 26-37/39
• WGK Germany: 3
• F: 3-10
• TSCA: No
• HazardClass: IRRITANT
• HS Code: 29339900