Butyl isocyanate , 98% , 111-36-4

Synonym(s):
n-Butyl isocyanate;1-Isocyanatobutane;BIC;Isocyanic acid butyl ester

Update time: 2022-07-08

Melting point:	85.5℃
Boiling point:	115 °C(lit.)
Density	0.88 g/mL at 25 °C(lit.)
vapor density	3 (vs air)
vapor pressure	10.6 mm Hg ( 20 °C)
refractive index	n20/D 1.406(lit.)
Flash point:	64 °F
storage temp.	2-8°C
form	Liquid
color	Colorless
explosive limit	1.3-10% (v/v)
Sensitive	Moisture Sensitive
Merck	13,1574
BRN	773917
Exposure limits	No exposure limit is set for this compound. On the basis of its low inhalation toxicity, a TLV-TWA value of 8 mg/m³ (2 ppm) can be safely ascribed.
InChIKey	HNHVTXYLRVGMHD-UHFFFAOYSA-N
CAS DataBase Reference	111-36-4(CAS DataBase Reference)
NIST Chemistry Reference	Butane, 1-isocyanato-(111-36-4)
EPA Substance Registry System	Butyl isocyanate (111-36-4)

n-Butyl isocyanate is used as an acylatingagent in the Friedel–Crafts reaction to produce amide.

Symbol(GHS)	GHS02,GHS05,GHS06,GHS08
Signal word	Danger
Hazard statements	H330-H311-H302-H314-H370-H317-H334-H225
Precautionary statements	P501-P272-P270-P240-P260-P210-P233-P243-P241-P242-P271-P264-P280-P284-P370+P378-P342+P311-P308+P311-P361+P364-P303+P361+P353-P333+P313-P301+P330+P331-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P233-P403+P235-P405
Hazard Codes	F,T+
Risk Statements	11-21/22-26-34-37-42/43
Safety Statements	23-26-28-36/37/39-45
RIDADR	UN 2485
WGK Germany	1
RTECS	NQ8250000
F	10-19-21
Autoignition Temperature	425°C
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	I
HS Code	29291090
Storage Class	3 - Flammable liquids
Hazard Classifications	Acute Tox. 1 Inhalation Acute Tox. 4 Oral Aquatic Chronic 3 Eye Dam. 1 Flam. Liq. 2 Resp. Sens. 1 Skin Corr. 1B Skin Sens. 1
Hazardous Substances Data	111-36-4(Hazardous Substances Data)
Toxicity	LC50 (4hr) in male, female rats (mg/m3): 60, 55 by inhalation (Pauluhn, Eben)
REACH Registrations	Active
Excepted Quantities	Forbidden