A1250712
Benzyl bromide , > 98.0%(GC), containing stabilizer epoxane , 100-39-0
Synonym(s):
α-Bromotoluene;Benzyl bromide
CAS NO.：100-39-0
Empirical Formula: C7H7Br
Molecular Weight: 171.03
MDL number: MFCD00000172
EINECS: 202-847-3
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -3 °C |
| Boiling point: | 198-199 °C(lit.) |
| Density | 1.44 g/mL at 20 °C |
| vapor density | 5.8 (vs air) |
| vapor pressure | 0.5 hPa (20 °C) |
| refractive index | n |
| Flash point: | 188 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with benzene, carbon tetrachloride, ethanol and ether. |
| form | Liquid |
| color | Clear colorless to yellow |
| Odor | Very sharp, pungent, like tear gas. |
| Sensitive | Moisture Sensitive/Light Sensitive |
| Merck | 14,1128 |
| BRN | 385801 |
| Henry's Law Constant | 1.4×10-3 mol/(m3Pa) at 25℃, HSDB (2015) |
| Dielectric constant | 5.1（20℃） |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChI | 1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2 |
| InChIKey | AGEZXYOZHKGVCM-UHFFFAOYSA-N |
| SMILES | BrCc1ccccc1 |
| CAS DataBase Reference | 100-39-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, (bromomethyl)-(100-39-0) |
| EPA Substance Registry System | Benzyl bromide (100-39-0) |
Description and Uses
Benzyl bromide is a combustible, colorless toyellow liquid with a pleasant odor. Molecularweight=171.05;Specific gravity (H2O:1) =1.438; Boilingpoint= 198℃; Freezing/Melting point =-4.0℃;Flashpoint =79℃ (cc). Hazard Identification (based on NFPA-704 M Rating System): Health 3, Flammability 2,Reactivity 1. Insoluble in water (slowly decomposes).
Making foaming and frothing agents, organic synthesis.
Safety
| Symbol(GHS) |    GHS05,GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H330-H314-H341-H335-H227 |
| Precautionary statements | P501-P202-P260-P210-P201-P271-P264-P280-P284-P370+P378-P308+P313-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P233-P403+P235-P405 |
| target organs | Respiratory system |
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 39-2 |
| RIDADR | UN 1737 |
| WGK Germany | 2 |
| RTECS | XS7965000 |
| F | 9-19-21 |
| TSCA | TSCA listed |
| HS Code | 2903 99 80 |
| HazardClass | 6.1 |
| PackingGroup | II |
| Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| Hazardous Substances Data | 100-39-0(Hazardous Substances Data) |
| Toxicity | dns-esc 1300 mmol/L ZKKOBW 92,177,78 |
| REACH Registrations | Active |
| Excepted Quantities | Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml) |
