1,1′-Bis(diisopropylphosphino)ferrocene , 98% , 97239-80-0

CAS NO.：97239-80-0

Empirical Formula: C22H36FeP210*

Molecular Weight: 418.31

MDL number: MFCD02684559

EINECS: 677-500-6

PRODUCT Properties

• Melting point: 50-52 °C(lit.)
• Flash point: >230 °F
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• form: Powder
• color: orange-yellow
• Water Solubility: Insoluble in water.
• InChI: InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3
• InChIKey: LPBBEMRSRONKMN-UHFFFAOYSA-N
• SMILES: P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
• CAS DataBase Reference: 97239-80-0(CAS DataBase Reference)

Description and Uses

1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280-P305+P351+P338-P304+P340-P405-P501A
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 37/39-26
• WGK Germany: 3
• TSCA: No
• HS Code: 29319090