(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane , 97% , 93379-49-8

Synonym(s):
(+)-trans-α,α′-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol);(+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol;(4S,5S)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane

CAS NO.：93379-49-8

Empirical Formula: C31H30O4

Molecular Weight: 466.57

MDL number: MFCD00010079

PRODUCT Properties

• Melting point: 193-196 °C(lit.)
• Boiling point: 633.2±50.0 °C(Predicted)
• alpha: -62.6 º (c=1 in chloroform)
• Density: 1.200±0.06 g/cm3(Predicted)
• storage temp.: Inert atmosphere,Room Temperature
• pka: 12.28±0.29(Predicted)
• form: powder to crystal
• color: White to Almost white
• optical activity: [α]19/D +67°, c = 1 in chloroform
• BRN: 4724097
• InChIKey: RNSJHECWLNVNFE-LOYHVIPDSA-N
• SMILES: C(O)(C1C=CC=CC=1)(C1C=CC=CC=1)[C@H]1OC(C)(C)O[C@@H]1C(O)(C1C=CC=CC=1)C1C=CC=CC=1 |&1:14,20,r|
• CAS DataBase Reference: 93379-49-8(CAS DataBase Reference)

Description and Uses

Ligand for enantioselective Lewis-acid mediated Diels-Alder, allyltitanation of aldehydes, and Michael-Mukaiyama additions promoted by chiral Ti-complexes.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H317-H319
• Precautionary statements: P280-P305+P351+P338
• Hazard Codes: Xn
• Risk Statements: 20/21/22-36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• HS Code: 29329990