Benzylmagnesium chloride solution , 2.0MinTHF , 6921-34-2

CAS NO.：6921-34-2

Empirical Formula: C7H7ClMg

Molecular Weight: 150.89

MDL number: MFCD00000469

EINECS: 230-039-0

PRODUCT Properties

• Boiling point: 182 °C(Press: 16 Torr)
• Density: 1.031 g/mL at 25 °C
• Flash point: 1 °F
• storage temp.: water-free area
• form: Liquid
• color: Brown to purple
• Water Solubility: Severe reaction
• Sensitive: Air & Moisture Sensitive
• BRN: 878506
• InChI: InChI=1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
• InChIKey: NRAFPLGJPPJUNB-UHFFFAOYSA-M
• SMILES: C1(C[Mg]Cl)=CC=CC=C1
• CAS DataBase Reference: 6921-34-2(CAS DataBase Reference)
• EPA Substance Registry System: Magnesium, chloro(phenylmethyl)- (6921-34-2)

Description and Uses

Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:

• For alkylating quinolyl-functionalized Cp?chromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts.
• In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.

Safety

• Symbol(GHS): GHS02,GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H371-H372-H303-H318-H333-H225-H314-H302-H336-H335-H351
• Precautionary statements: P260h-P303+P361+P353-P501a-P210-P280-P305+P351+P338-P310-P261-P260-P370+P378-P403+P235-P233-P240-P241+P242+P243-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P403+P233-P405-P501
• Hazard Codes: F+,C,Xi,F
• Risk Statements: 12-14-34-66-67-36/37-19-11-14/15-40-37-17-22
• Safety Statements: 16-29-33-7/8-45-43-36/37/39-26-6A-43B
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 1
• F: 1-3-10
• TSCA: Yes
• HazardClass: 4.3
• PackingGroup: II
• HS Code: 29319090
• Excepted Quantities: Not Permitted as Excepted Quantity