A2393012
Chlorobis(cyclooctene)rhodium(I),dimer , 98% , 12279-09-3
Synonym(s):
[Rh(coe)2Cl]2
CAS NO.：12279-09-3
Empirical Formula: C32H56Cl2Rh2
Molecular Weight: 717.5
MDL number: MFCD00013287
EINECS: 623-340-7
| Pack Size | Price | Stock | Quantity |
| 100MG | RMB396.00 | In Stock |
|
| 500MG | RMB1644.80 | In Stock |
|
| 1g | RMB3290.40 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 190 °C (dec.) (lit.) |
| storage temp. | Freezer |
| form | crystal |
| color | orange to red |
| optical activity | -0.60°(C=0.01g/ml CHCL3) |
| Sensitive | air sensitive, store cold |
| InChI | 1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;; |
| InChIKey | GQPAPAIPOLEZHT-XFCUKONHSA-L |
| SMILES | Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4 |
| CAS DataBase Reference | 12279-09-3 |
Description and Uses
Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22-36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
