Cyclopropylboronic acid , 90% , 411235-57-9

Synonym(s):
Cyclopropaneboronic acid

CAS NO.：411235-57-9

Empirical Formula: C3H7BO2

Molecular Weight: 85.9

MDL number: MFCD04038750

EINECS: 609-890-0

PRODUCT Properties

• Melting point: 90-95 °C (lit.)
• Boiling point: 205.1±23.0 °C(Predicted)
• Density: 1.11±0.1 g/cm3(Predicted)
• storage temp.: -20°C
• solubility: DMSO
• form: Powder
• pka: 10.49±0.20(Predicted)
• color: white
• Sensitive: moisture sensitive
• InChI: InChI=1S/C3H7BO2/c5-4(6)3-1-2-3/h3,5-6H,1-2H2
• InChIKey: WLVKDFJTYKELLQ-UHFFFAOYSA-N
• SMILES: C1CC1B(O)O
• CAS DataBase Reference: 411235-57-9(CAS DataBase Reference)

Description and Uses

Reagent used for• ;Microwave-assisted copper(II)-catalyzed N-cyclopropylation1• ;Nickel- and copper-catalyzed Suzuki-Miyaura coupling reaction of arenes2• ;Palladacycle-catalyzed Suzuki-cross coupling of aryl halides with cyclopropylboronic acid3• ;Palladium(0)-catalyzed cyclopropane C-H bond functionalization4• ;Palladium-catalyzed decarboxylative coupling5• ;Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes6• ;Palladium-catalyzed Suzuki coupling reaction7Reagent used in Preparation of• ;Diaryl ketones by arylation

Safety

• Symbol(GHS): GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H315-H319-H335-H302-H318-H360FD
• Precautionary statements: P201-P280-P305+P351+P338-P308+P313-P261-P280a-P304+P340-P405-P501a
• Hazard Codes: Xn,T
• Risk Statements: 22-36-61-60-36/37/38
• Safety Statements: 26-36-45-53-37/39
• WGK Germany: 3
• TSCA: No
• HazardClass: IRRITANT, IRRITANT-HARMFUL
• HS Code: 29319090