A3125112
Diethyl carbonate , 99% , 105-58-8
Synonym(s):
Diethyl carbonate;DEC;Diethyl ester;CED;TGFB1
CAS NO.：105-58-8
Empirical Formula: C5H10O3
Molecular Weight: 118.13
MDL number: MFCD00009107
EINECS: 203-311-1
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -43 °C (lit.) |
| Boiling point: | 126-128 °C (lit.) |
| Density | 0.975 g/mL at 25 °C (lit.) |
| vapor density | 4.1 (vs air) |
| vapor pressure | 10 mm Hg ( 23.8 °C) |
| refractive index | n |
| Flash point: | 88 °F |
| storage temp. | no restrictions. |
| solubility | 18.8mg/l insoluble |
| form | Liquid |
| color | Clear |
| PH | 6.3 (1g/l, H2O) |
| Odor | Pleasant, etheral; mild and nonresidual. |
| explosive limit | 1.4-11.0%(V) |
| biological source | mouse |
| Water Solubility | Negligible |
| Sensitive | Moisture Sensitive |
| Merck | 14,3780 |
| BRN | 956591 |
| Dielectric constant | 2.8（Ambient） |
| Stability: | Stable. Flammable. Incompatible with strong acids, strong bases, reducing agents, oxidizing agents. Protect from moisture. |
| LogP | 1.21 at 25℃ |
| Surface tension | 29.2 mN/m at 273.18K |
| CAS DataBase Reference | 105-58-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Carbonic acid, diethyl ester(105-58-8) |
| EPA Substance Registry System | Diethyl carbonate (105-58-8) |
Description and Uses
Diethyl carbonate (DEC) is generally used in the C-alkoxycarbonylation of enolate anions, aryl and alkyl cyanides. It reacts with 1,2-amino alcohols to yield corresponding 2-oxazolidinones. Additionally, DEC is also used as a component of electrolyte solution in lithium ion batteries.
Safety
| Symbol(GHS) |  GHS02 |
| Signal word | Warning |
| Hazard statements | H226 |
| Precautionary statements | P210-P233-P240-P241-P242-P243 |
| Hazard Codes | T,Xi |
| Risk Statements | 23/24/25-36/37/38-10 |
| Safety Statements | 26-36-45-16-23 |
| RIDADR | UN 2811 6.1/PG 2 |
| WGK Germany | 3 |
| RTECS | YE1050000 |
| F | 21 |
| Autoignition Temperature | 445 °C |
| TSCA | Yes |
| HS Code | 2920 90 10 |
| HazardClass | 3 |
| PackingGroup | III |
| Hazardous Substances Data | 105-58-8(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: > 4900 mg/kg LC50 (inhalation) > 21 mg/kg (mouse) TDL0 500 mg/kg (mouse) LD50 (s.c.) 8500 mg/kg (rat) |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
