Diphenyl phosphoryl azide , 97% , 26386-88-9

Synonym(s):
DPPA;12-Deoxyphorbol 13-phenylacetate 20-acetate;DPPA polymer-bound;Phosphoric acid diphenyl ester azide;PS-DPPA

CAS NO.：26386-88-9

Empirical Formula: C12H10N3O3P

Molecular Weight: 275.2

MDL number: MFCD00001987

EINECS: 247-644-0

PRODUCT Properties

• Boiling point: 157 °C/0.17 mmHg (lit.)
• Density: 1.277 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.551(lit.)
• Flash point: >230 °F
• storage temp.: 2-8°C
• solubility: Acetonitrile (Slightly), Chloroform (Slightly), Ethyl Acetate (Sparingly)
• form: Liquid
• Specific Gravity: 1.277
• color: slightly yellow
• Water Solubility: insoluble
• Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
• BRN: 2058967
• Stability: Stable. Incompatible with acids, strong oxidizing agents.
• InChIKey: SORGEQQSQGNZFI-UHFFFAOYSA-N
• CAS DataBase Reference: 26386-88-9(CAS DataBase Reference)
• NIST Chemistry Reference: Diphenylphosphoryl azide(26386-88-9)

Description and Uses

Diphenylphosphoryl azide (DPPA or diphenyl phosphorazidate, (PhO)2P(O)N3) is a very toxic and potentially explosive organic compound. DPPA has been found to be effective for a variety of organic reactions as a versatile synthetic reagent. It is widely used in synthesis of other organic compounds especially as a reagent for the synthesis of peptides by virtue of its reactions with carboxylic acids leading to either the urethane or the amide.

Safety

• Symbol(GHS): GHS06
• Signal word: Danger
• Hazard statements: H301+H311+H331-H315-H319-H335
• Precautionary statements: P261-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338
• Hazard Codes: T
• Risk Statements: 23/24/25-36/37/38
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3278 6.1/PG 2
• WGK Germany: 3
• F: 3-10
• Hazard Note: Toxic/Keep Cold
• TSCA: No
• HazardClass: 6.1
• PackingGroup: III
• HS Code: 29299000
• Limited Quantities: 100ml (liquid) or 0.5 Kg (solid)
• Excepted Quantities: Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)