Home Categories Organic Chemistry Di-n-butylmagnesium solution
A3405912

Di-n-butylmagnesium solution , 1.0Minheptane , 1191-47-5

CAS NO.:1191-47-5

Empirical Formula: C8H18Mg

Molecular Weight: 138.54

MDL number: MFCD00015225

EINECS: 214-736-7

Pack Size Price Stock Quantity
100ML RMB399.20 In Stock
500ML RMB1919.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: -71 °C
Density  0.749 g/mL at 20 °C
Flash point: 21 °F
storage temp.  2-8°C
form  solution
BRN  3535184
InChI InChI=1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
InChIKey ODHFJIDDBSDWNU-UHFFFAOYSA-N
SMILES [Mg](CCCC)CCCC
CAS DataBase Reference 1191-47-5
EPA Substance Registry System Magnesium, dibutyl- (1191-47-5)

Description and Uses

Electrochemically inactive [Mg2(μ-Cl)3.6THF][C2H5AlCl3] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS2 or WO2Cl2. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H224-H250-H260-H302-H304-H314-H336-H361f-H373-H412-H225-H410
Precautionary statements  P210-P231+P232-P280-P301+P310-P302+P334-P303+P361+P353-P304+P340+P310-P305+P351+P338-P331-P370+P378-P403+P235-P422
target organs Central nervous system
Hazard Codes  F+,C,T,F,N
Risk Statements  12-14/15-22-34-66-67-48/20/22-40-39/23/24/25-23/24/25-11-10-65-50/53-17-19-62-52/53-48/20
Safety Statements  16-26-36/37/39-43-45-7/8-62-61-60
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
1-3-10
TSCA  TSCA listed
HS Code  29310099
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 3
Asp. Tox. 1
Eye Dam. 1
Flam. Liq. 1
Pyr. Liq. 1
Repr. 2
Skin Corr. 1B
STOT SE 3
Water-react 1

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