A3559212
Diethyl Diallylmalonate , >98.0%(GC) , 3195-24-2
CAS NO.：3195-24-2
Empirical Formula: C13H20O4
Molecular Weight: 240.3
MDL number: MFCD00009126
EINECS: 221-696-4
| Pack Size | Price | Stock | Quantity |
| 5ML | RMB135.20 | In Stock |
|
| 10ML | RMB239.20 | In Stock |
|
| 25ML | RMB535.20 | In Stock |
|
| 50ML | RMB991.20 | In Stock |
|
| 100ml | RMB1599.20 | In Stock |
|
| 250ML | RMB3463.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 128-130 °C/12 mmHg (lit.) |
| Density | 0.994 g/mL at 25 °C (lit.) |
| vapor pressure | 4.266Pa at 25℃ |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform, DMSO, Methanol |
| form | Oil |
| color | Clear Colourless |
| Water Solubility | Sparingly Soluble in water. (0.72 g/L) (25°C) |
| BRN | 1790529 |
| InChI | 1S/C13H20O4/c1-5-9-13(10-6-2,11(14)16-7-3)12(15)17-8-4/h5-6H,1-2,7-10H2,3-4H3 |
| InChIKey | LYUUVYQGUMRKOV-UHFFFAOYSA-N |
| SMILES | CCOC(=O)C(CC=C)(CC=C)C(=O)OCC |
| LogP | 3.46 |
| CAS DataBase Reference | 3195-24-2(CAS DataBase Reference) |
Description and Uses
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| HS Code | 2917198090 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
