3-Methoxybenzyl bromide , 98% , 874-98-6

Synonym(s):
1-Bromomethyl-3-methoxybenzene

CAS NO.：874-98-6

Empirical Formula: C8H9BrO

Molecular Weight: 201.06

MDL number: MFCD00216590

PRODUCT Properties

• Boiling point: 152 °C(lit.)
• Density: 1.436 g/mL at 25 °C(lit.)
• refractive index: n20/D 1.575(lit.)
• Flash point: >230 °F
• storage temp.: -20°C Freezer
• solubility: soluble in Chloroform
• form: Liquid
• color: Clear colorless to light yellow
• CAS DataBase Reference: 874-98-6(CAS DataBase Reference)

Description and Uses

3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:

• 6-(3-methoxyphenyl)-hexane-2,4-dione
• N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
• 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
• 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
• Hazard Codes: C
• Risk Statements: 34
• Safety Statements: 26-27-36/37/39-45
• RIDADR: UN 3265 8/PG 2
• WGK Germany: 3
• Hazard Note: Corrosive
• HazardClass: 8
• HS Code: 29049090
• Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)