A4975012
1-Iodo-3-nitrobenzene , 98% , 645-00-1
CAS NO.：645-00-1
Empirical Formula: C6H4INO2
Molecular Weight: 249.01
MDL number: MFCD00007218
EINECS: 211-427-9
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 36-38 °C (lit.) |
| Boiling point: | 280 °C (lit.) |
| Density | 1.9477 |
| Flash point: | 161 °F |
| storage temp. | Refrigerator (+4°C) + Flammables area |
| form | powder to lump to clear liquid |
| color | Light yellow to Yellow |
| Water Solubility | insoluble |
| Sensitive | Light Sensitive |
| BRN | 1525167 |
| Stability: | Stable. Highly flammable. Incompatible with strong bases, strong oxidizing agents. |
| CAS DataBase Reference | 645-00-1(CAS DataBase Reference) |
| NIST Chemistry Reference | m-Iodonitrobenzene(645-00-1) |
| EPA Substance Registry System | m-Iodonitrobenzene (645-00-1) |
Description and Uses
1-Iodo-3-nitrobenzene was used in the synthesis of 5-substituted pyrrolo[3,2-b]pyridine amide and 3′-nitro-4-methylthiobiphenyl. It was used in palladium(0) catalyzed cross-coupling reaction between heteroarylzinc iodide and unsaturated iodide.
Safety
| Symbol(GHS) |   GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H228-H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P210-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 |
| Hazard Codes | Xn,F,Xi |
| Risk Statements | 20/21/22-36/37/38-36-33-11 |
| Safety Statements | 26-36/37/39-45-16-36 |
| RIDADR | UN 1325 4.1/PG 2 |
| WGK Germany | 3 |
| TSCA | Yes |
| HazardClass | 4.1 |
| HS Code | 29049090 |
| Limited Quantities | 1.0 Kg (2.2 lbs) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
