(R)-(+)-4-Methoxy-α-methylbenzylamine , 98% , 22038-86-4

Synonym(s):
(R)-(+)-1-(4-Methoxyphenyl)ethylamine

CAS NO.：22038-86-4

Empirical Formula: C9H13NO

Molecular Weight: 151.21

MDL number: MFCD00671659

EINECS: 606-907-3

PRODUCT Properties

• Melting point: <-20°C
• Boiling point: 65°C 0,4mm
• alpha: 32 º (neat)
• Density: 1.024 g/mL at 20 °C(lit.)
• refractive index: n20/D 1.533
• Flash point: 65°C/0.38mm
• storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• form: liquid
• pka: 9.29±0.10(Predicted)
• Appearance: Colorless to light yellow Liquid
• Water Solubility: Soluble in water (10g/L).
• Sensitive: Air Sensitive
• BRN: 2413029
• InChI: InChI=1/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/s3
• InChIKey: JTDGKQNNPKXKII-SSDOTTSWSA-N
• SMILES: [C@@H](C1C=CC(OC)=CC=1)(N)C |&1:0,r|
• CAS DataBase Reference: 22038-86-4(CAS DataBase Reference)

Description and Uses

(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:

• Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
• Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
• N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.

Safety

• Symbol(GHS): GHS05,GHS07
• Signal word: Danger
• Hazard statements: H302-H314-H317-H412
• Precautionary statements: P261-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
• Hazard Codes: C
• Risk Statements: 34-22
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 2735 8/PG 3
• WGK Germany: 3
• F: 10-34
• HazardClass: 8
• PackingGroup: III
• HS Code: 29222990
• Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)