A5578512
1-Methyl-2-propenylmagnesium chloride solution , 0.5MinTHF , 21969-32-4
| Pack Size | Price | Stock | Quantity |
| 100ML | RMB447.20 | In Stock |
|
| 500ML | RMB1788.80 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 67 °C |
| Density | 0.917 g/mL at 25 °C |
| Flash point: | −4 °F |
| InChI | 1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1 |
| InChIKey | RTJGBPYEBKZQGE-UHFFFAOYSA-M |
| SMILES | CC([Mg]Cl)C=C |
Description and Uses
1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.
Safety
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H261-H302-H314-H335-H351 |
| Precautionary statements | P210-P231+P232-P280-P370+P378-P402+P404-P403+P235 |
| target organs | Respiratory system |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | F,C,Xn |
| Risk Statements | 11-14-19-20/21/22-34-40-36/37/38-14/15 |
| Safety Statements | 16-26-27-36/37/39-45-43-36/37 |
| RIDADR | UN 3399 4.3/PG 2 |
| WGK Germany | 3 |
| HS Code | 29319090 |
| Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water |
| Hazard Classifications | Acute Tox. 4 Oral Carc. 2 Flam. Liq. 2 Skin Corr. 1B STOT SE 3 Water-react 2 |
