1-Nitropropane , 98% , 108-03-2
Synonym(s):
1-Nitropropane;N-Nitropropane
CAS NO.：108-03-2
Empirical Formula: C3H7NO2
Molecular Weight: 89.09
MDL number: MFCD00007407
EINECS: 203-544-9
PRODUCT Properties
| Melting point: | -108 °C |
| Boiling point: | 132 °C |
| Density | 0.998 g/mL at 25 °C(lit.) |
| vapor density | 3.1 (vs air) |
| vapor pressure | 7.5 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | 93 °F |
| storage temp. | Store below +30°C. |
| solubility | 14g/l |
| pka | pK1:8.98 (25°C) |
| form | Liquid |
| color | Clear |
| PH | 6.0 (0.9g/l, H2O, 20℃) |
| explosive limit | 2.2-11.0%(V) |
| Water Solubility | 1.40 g/100 mL |
| Merck | 14,6626 |
| BRN | 506236 |
| Henry's Law Constant | 6.11 at 25 °C (static headspace-GC, Welke et al., 1998) |
| Exposure limits | NIOSH REL: TWA 25 ppm (90 mg/m3), IDLH 1,000 ppm; OSHA PEL: TWA
25 ppm; ACGIH TLV: TWA 25 ppm (adopted). |
| Dielectric constant | 23.239999999999998 |
| Stability: | Stable. Flammable. Incompatible with strong bases, strong oxidizing agents. |
| InChIKey | JSZOAYXJRCEYSX-UHFFFAOYSA-N |
| LogP | 0.79 at 22℃ |
| Surface tension | 29.4mN/m at 20°C |
| CAS DataBase Reference | 108-03-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Propane, 1-nitro-(108-03-2) |
| EPA Substance Registry System | 1-Nitropropane (108-03-2) |
Description and Uses
1-Nitropropane (1-NP), a representative small nitro-alkane, is widely used as an industrial solvent and a fuel additive in automobiles and aircraft engines. The improvement effects of 1-NP on fuel combustion demonstrate that 1-NP served as an initiator can rapidly produce a large number of reactive radicals, which significantly increases the fuel conversion rate. In addition, among the small nitro-alkanes, the molecular structure of 1-NP endows it with a higher specific impulse. It provides the possibilities for its application as propellant in long-range rocket systems[1].
The solvent of 1-Nitropropane is mainly used coatings, inks and separation processes.
Safety
| Symbol(GHS) |   GHS02,GHS06 |
| Signal word | Danger |
| Hazard statements | H226-H302+H312-H331 |
| Precautionary statements | P210-P233-P280-P301+P312-P303+P361+P353-P304+P340+P311 |
| Hazard Codes | Xn |
| Risk Statements | 10-20/21/22 |
| Safety Statements | 9-24/25 |
| RIDADR | UN 2608 3/PG 3 |
| OEB | A |
| OEL | TWA: 25 ppm (90 mg/m3) |
| WGK Germany | 1 |
| RTECS | TZ5075000 |
| Autoignition Temperature | 788 °F |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29042000 |
| Hazardous Substances Data | 108-03-2(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 455 mg/kg LD50 dermal Rabbit > 2000 mg/kg |
| IDLA | 1,000 ppm |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
