A6681512
Pyrrolidine , 99% , 123-75-1
Synonym(s):
PRL;Pyrrolidine;Tetrahydropyrrole;Tetramethyleneimine
CAS NO.：123-75-1
Empirical Formula: C4H9N
Molecular Weight: 71.12
MDL number: MFCD00005249
EINECS: 204-648-7
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -63 °C |
| Boiling point: | 87-88 °C/760 mmHg (lit.) |
| Density | 0.852 g/mL at 25 °C (lit.) |
| vapor density | 2.45 (vs air) |
| vapor pressure | 128 mm Hg ( 39 °C) |
| FEMA | 3523 | PYRROLIDINE |
| refractive index | n |
| Flash point: | 37 °F |
| storage temp. | Store below +30°C. |
| solubility | water: miscible |
| form | Liquid |
| pka | 11.27(at 25℃) |
| color | Colorless to Almost colorless |
| Odor | at 0.10 % in propylene glycol. ammoniacal animal egg amine |
| PH | 12.9 (100g/l, H2O, 20℃) |
| explosive limit | 1.6-10.6%(V) |
| Odor Type | ammoniacal |
| biological source | synthetic |
| Water Solubility | Miscible with alcohol, ether, chloroform and water. |
| Sensitive | Air Sensitive |
| Merck | 14,8015 |
| JECFA Number | 1609 |
| BRN | 102395 |
| Dielectric constant | 8.3000000000000007 |
| Stability: | Stable; flammable. Incompatible with strong acids, strong oxidizing agents. |
| InChIKey | RWRDLPDLKQPQOW-UHFFFAOYSA-N |
| LogP | 0.22 at 25℃ |
| Surface tension | 30.11mN/m at 293.15K |
| CAS DataBase Reference | 123-75-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Pyrrolidine(123-75-1) |
| EPA Substance Registry System | Pyrrolidine (123-75-1) |
Description and Uses
Pyrrolidine is a flammable alkaline liquid that undergoes reactions typical of secondary amines. It is used to prepare pesticides and rubber accelerators and as a chemical intermediate (usually the hydrochloride form) in the pharmaceutical industry. There is relatively limited industrial exposure to this material.
Safety
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225-H302+H332-H314 |
| Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | F,T,C |
| Risk Statements | 11-22-23-34-35-20/21/22-20/22-R35-R20/21/22-R11 |
| Safety Statements | 16-26-36/37/39-45-33-S45-S36/37/39-S26-S16 |
| RIDADR | UN 1922 3/PG 2 |
| WGK Germany | 2 |
| RTECS | UX9650000 |
| F | 34 |
| Autoignition Temperature | 653 °F |
| TSCA | Yes |
| HS Code | 2933 99 80 |
| HazardClass | 3 |
| PackingGroup | II |
| Hazardous Substances Data | 123-75-1(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 433 mg/kg |
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
