2-Picoline borane complex , 95% , 3999-38-0

Synonym(s):
2-Picoline borane complex;2-Picoline borane complex solution

CAS NO.：3999-38-0

Empirical Formula: C6H10BN

Molecular Weight: 106.96

MDL number: MFCD07784361

EINECS: 609-767-1

PRODUCT Properties

• Melting point: 48 °C
• Density: 1.297 g/mL at 25 °C
• Flash point: 100°(212°F)
• storage temp.: 2-8°C
• solubility: Dichloromethane (Sparingly), Ethyl Acetate (Slightly)
• form: Solid
• color: White
• Water Solubility: Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
• Sensitive: Moisture Sensitive
• InChI: InChI=1S/C6H10BN/c1-6-4-2-3-5-8(6)7/h2-5H,1,7H3
• InChIKey: ZMASBEFBIXMNCP-UHFFFAOYSA-N
• SMILES: [B+3](N1=CC=CC=C1C)([H-])([H-])[H-]

Description and Uses

Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

Safety

• Symbol(GHS): GHS02,GHS07
• Signal word: Danger
• Hazard statements: H261-H315-H319-H335
• Precautionary statements: P231+P232-P302+P352-P305+P351+P338
• Hazard Codes: F,Xn,Xi
• Risk Statements: 14/15-40-36/37/38-26
• Safety Statements: 36/37-43-26-36/37/38-14/15
• RIDADR: UN 3130 6.1(4.3) / PGII
• WGK Germany: 3
• HazardClass: 4.3
• PackingGroup: II
• HS Code: 29333990
• Limited Quantities: 0.5 Kg (1.1 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)