6-(γ,γ-Dimethylallylamino)purine , 10mMinDMSO , 2365-40-4

CAS NO.：2365-40-4

Empirical Formula: C10H13N5

Molecular Weight: 203.24

MDL number: MFCD00132998

EINECS: 812-988-8

PRODUCT Properties

• Melting point: 218-220 °C
• Boiling point: 318.1±52.0 °C(Predicted)
• Density: 1.28±0.1 g/cm3(Predicted)
• storage temp.: -20°C
• solubility: DMF (Slightly), Methanol (Slightly)
• form: Solid
• pka: 9.36±0.20(Predicted)
• color: White to Off-White
• InChI: InChI=1S/C10H13N5/c1-7(2)3-4-11-9-8-10(13-5-12-8)15-6-14-9/h3,5-6H,4H2,1-2H3,(H2,11,12,13,14,15)
• InChIKey: HYVABZIGRDEKCD-UHFFFAOYSA-N
• SMILES: N1C2C(=NC=NC=2NC/C=C(\C)/C)NC=1

Description and Uses

A purine alkaloid, this base was first isolated from the leaves of Gleditsia triacanthus L., and subsequently discovered in Chidlowia sanguinea and Holar_x0002_rhena floribunda (G. Don.) Dur. et Schinz. The free alkaloid forms colourless crystals and yields crystalline salts and derivatives, e.g. the hydrochloride, m.p. 218-9°C; hydrobromide, m.p. 215-6°C; sulphate, two salts are formed with m.p. 175-6°C and 216-7°C respectively depending upon the amount of acid used in their preparation; picrate, m.p. 246-7°C (dec.); picrolonate, m.p. 229-231 0 C; methiodide, m.p. 227-9°C and the N-benzyl derivative, m.p. 150°C. Oxidation of the alkaloid with KMn04 gives 7-(2:3-dihydroxy-3-methylbutyl)-6-aminopurine which, on periodate oxidation, furnishes 7-(formylmethyl)- 6-aminopurine and Me2CO. Heating the base with Ba(OHh gives one mole each of NH3, C02 and 4-N-(r:r-dimethylallyl)-N-amino-imidazole-5-carboxamide.

N6-(2-Isopentenyl)adenine can be used in biological study for cytokinins stimulated expression of stress-related proteins and transcripts in Arabidopsis thaliana with isopentenyltransferase overexpression.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P271-P280
• WGK Germany: 3
• HS Code: 2933599590