Sodium amide , 95% , 7782-92-5

Synonym(s):
Sodium amide crystalline

CAS NO.：7782-92-5

Empirical Formula: H2NNa

Molecular Weight: 39.01

MDL number: MFCD00011117

EINECS: 231-971-0

PRODUCT Properties

• Melting point: 210 °C (lit.)
• Boiling point: 400 °C (lit.)
• Density: 1.39 g/cm3 (25℃)
• Flash point: 85 °F
• storage temp.: Store below +30°C.
• solubility: reacts with H2O
• form: crystalline
• color: Greyish white powder
• Odor: Ammonia like
• Water Solubility: REACTS VERY VIOLENTLY, EVEN EXPLOSIVELY
• Sensitive: Air & Moisture Sensitive
• Merck: 14,8576
• Stability: Stability Flammable. Reacts violently with water producing very toxic fumes. In case of fire do not use water, but instead smother with soda ash. May form explosive peroxides if heated, or if stored for extended periods in contact with air or oxygen. Incompatible with water and aqueous solutions, carbon dioxide, halogenated hydrocarbo
• InChI: 1S/H2N.Na/h1H2;/q-1;+1
• InChIKey: ODZPKZBBUMBTMG-UHFFFAOYSA-N
• SMILES: N[Na]
• CAS DataBase Reference: 7782-92-5(CAS DataBase Reference)
• EPA Substance Registry System: Sodium amide (Na(NH2)) (7782-92-5)

Description and Uses

Reagent for: Synthesis of allylic amines and amides1 Synthesis of antibacterials2 Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Safety

• Symbol(GHS): GHS02,GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H225-H261-H304-H314-H336-H361d-H373-H412
• Precautionary statements: P210-P231+P232-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
• PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
• Hazard Codes: F,C,Xi,N
• Risk Statements: 14/15-19-34-20/21-10-67-65-63-48/20-11-36/37-15/29-14-50-29
• Safety Statements: 26-43-45-62-7/8-43D-36/37/39-27-16-61
• RIDADR: UN 3129 4.3/PG 2
• WGK Germany: 2
• F: 3-10-23
• Autoignition Temperature: 450 °C
• TSCA: TSCA listed
• HS Code: 2853 90 90
• HazardClass: 4.3
• PackingGroup: II
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Hazard Classifications: Aquatic Chronic 3; Eye Dam. 1; Skin Corr. 1B; Water-react 2
• Hazardous Substances Data: 7782-92-5(Hazardous Substances Data)
• Limited Quantities: 0.5 Kg (1.1 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)