PRODUCT Properties
| Melting point: | ≥300 °C(lit.) |
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| Boiling point: | 1150 °C |
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| Density | 5.852 g/mL at 25 °C(lit.) |
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| Flash point: | 1150°C |
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| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
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| solubility | Methanol (Slightly), Water (Slightly) |
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| form | solid |
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| color | orange to brown |
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| Specific Gravity | 5.852 |
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| Water Solubility | 182 g/100 mL (15.5 ºC) |
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| Sensitive | Moisture Sensitive & Hygroscopic |
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| Crystal Structure | NaCl type |
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| crystal system | Cube |
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| Merck | 14,8514 |
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| Space group | Fm3m |
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| Lattice constant |
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| Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 2.5 mg/m3 NIOSH: IDLH 10 mg/m3; IDLH 250 mg/m3; TWA 0.01 mg/m3 |
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| Stability: | Stable. Incompatible with strong oxidizing agents, strong acids, reducing agents. Light sensitive. Hygroscopic. |
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| Major Application | PEM fuel cells material synthesis precursor |
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| InChI | 1S/Ag.FH/h;1H/q+1;/p-1 |
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| InChIKey | REYHXKZHIMGNSE-UHFFFAOYSA-M |
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| SMILES | F[Ag] |
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| CAS DataBase Reference | 7775-41-9(CAS DataBase Reference) |
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| NIST Chemistry Reference | Silver monofluoride(7775-41-9) |
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| EPA Substance Registry System | Silver fluoride (7775-41-9) |
Description and Uses
Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.
Safety
| Symbol(GHS) |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Hazard Codes | C |
| Risk Statements | 34-23/24/25-35 |
| Safety Statements | 26-36/37/39-45-25-28 |
| RIDADR | UN 3260 8/PG 2 |
| WGK Germany | 3 |
| RTECS | VW4250000 |
| F | 3-8-10-21 |
| Hazard Note | Corrosive |
| TSCA | TSCA listed |
| HazardClass | HYGROSCOPIC, CORROSIVE |
| HazardClass | 8 |
| HS Code | 28432900 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Skin Corr. 1B |
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
