Home Categories (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine
SDS-US
A7398112

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine , ≥97% , 185449-80-3

Synonym(s):
(S)-MonoPhos

CAS NO.：185449-80-3

Empirical Formula: C22H18NO2P

Molecular Weight: 359.36

MDL number: MFCD03426988

Pack Size Price Stock Quantity
250MG RMB32.00 In Stock
1G RMB102.40 In Stock
5G RMB340.80 In Stock
25g RMB1331.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 190 °C (dec.)
Boiling point: 548.7±33.0 °C(Predicted)
alpha  +587° (c 0.06, CHCl3)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  crystal
pka 1.22±0.20(Predicted)
color  white
optical activity Consistent with structure
Sensitive  moisture sensitive
InChI InChI=1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3
InChIKey QCHAVHXSBZARBO-UHFFFAOYSA-N
SMILES O1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1N(C)C)C=CC=C3

Description and Uses

1. Asymmetric hydrogenation of ketones and β-keto esters.
2. Light-induced, enantioselective hydrogenation.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H412
Precautionary statements  P273
Safety Statements  22-24/25
WGK Germany  3
HS Code  2929.90.5090

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