Home Categories Chemical Reagents Tetramethylammonium bromide
A7726412

Tetramethylammonium bromide , AR , 64-20-0

Synonym(s):
TBAB

CAS NO.:64-20-0

Empirical Formula: C4H12BrN

Molecular Weight: 154.05

MDL number: MFCD00011626

EINECS: 200-581-2

Pack Size Price Stock Quantity
25G RMB24.00 In Stock
100G RMB70.40 In Stock
500G RMB310.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: >300 °C (lit.)
Boiling point: >360°C
bulk density 450kg/m3
Density  1,56 g/cm3
refractive index  1.4379 (estimate)
storage temp.  Store below +30°C.
solubility  H2O: 0.1 g/mL, clear, colorless
form  Crystalline Powder
color  Slightly gray
PH 5.5-6.5 (100g/l, H2O)
Odor Odorless
Water Solubility  soluble
Sensitive  Hygroscopic
λmax λ: 240 nm Amax: 0.06
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02
BRN  3620955
CAS DataBase Reference 64-20-0(CAS DataBase Reference)
NIST Chemistry Reference Tetramethylammonium bromide(64-20-0)
EPA Substance Registry System Methanaminium, N,N,N-trimethyl-, bromide (64-20-0)

Description and Uses

Tetrabutylammonium bromide (TBAB) may be used in the molten state in the following processes:

  • Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
  • Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
  • Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
  • Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
  • Catalyze the addition of thiols to conjugated alkenes.
  • Dehydrochlorination of poly(vinyl chloride).

Safety

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H300
Precautionary statements  P301+P330+P331+P310
Hazard Codes  T
Risk Statements  25-36/37/38
Safety Statements  26-28-36-45-37/39-28A
RIDADR  UN 2811 6.1/PG 2
WGK Germany  3
RTECS  BS7600000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29239000
Limited Quantities 100ml (liquid) or 0.5 Kg (solid)
Excepted Quantities Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)

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