Tri-tert-butylphosphonium tetrafluoroborate , 97% , 131274-22-1

Synonym(s):
[(t-Bu)₃PH]BF₄;TTBP · HBF₄

CAS NO.：131274-22-1

Empirical Formula: C12H28P.BF4

Molecular Weight: 290.13

MDL number: MFCD04039975

EINECS: 672-603-2

PRODUCT Properties

• Melting point: 261 °C(lit.)
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• solubility: Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
• form: Crystals and Chunks
• color: White
• Water Solubility: Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
• Sensitive: Hygroscopic
• BRN: 8813613
• InChI: InChI=1S/C12H28P.BF4/c1-10(2,3)13(11(4,5)6)12(7,8)9;2-1(3,4)5/h13H,1-9H3;/q2*-1
• InChIKey: YSTLBJVHZMEEAC-UHFFFAOYSA-N
• SMILES: [P-](C(C)(C)C)(C(C)(C)C)C(C)(C)C.[B-](F)(F)(F)F
• CAS DataBase Reference: 131274-22-1(CAS DataBase Reference)

Description and Uses

Tri-tert-butylphosphonium Tetrafluoroborate is used in the synthesis of substituted biaryl compounds via palladium catalyzed tandem Heck-direct arylation and tandem- sequential Heck-direct arylation-hydrogenation. Also used in the synthesis of a novel organic dye with fluorenone as conjugation bridge which is used in dye sensitized solar cells.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Hazard Codes: Xn
• Risk Statements: 36/37/38-20/21/22
• Safety Statements: 22-24/25-36/37/39-26
• RIDADR: UN 1759 8/PG III
• WGK Germany: 3
• TSCA: No
• HazardClass: 8
• PackingGroup: III
• HS Code: 29319090