4-Acryloylmorpholine , Electronic grade, 99.9999%MetalsBasis , 5117-12-4

Synonym(s):
1-(Morpholin-4-yl)propenone;1-Morpholinoprop-2-en-1-one;4-(1-Oxo-2-propenyl)morpholine;4-Acryloylmorpholine;Acryloylmorpholine

CAS NO.：5117-12-4

Empirical Formula: C7H11NO2

Molecular Weight: 141.17

MDL number: MFCD00047413

EINECS: 418-140-1

PRODUCT Properties

• Melting point: −35 °C(lit.)
• Boiling point: 158°C 50mm
• Density: 1.122 g/mL at 25 °C(lit.)
• vapor pressure: 1.03-1.64Pa at 25-29.9℃
• refractive index: n20/D 1.512(lit.)
• Flash point: >230 °F
• storage temp.: 2-8°C
• solubility: Soluble in water
• form: Liquid
• pka: -1.08±0.20(Predicted)
• color: Colorless to yellow
• Water Solubility: 1000g/L at 20℃
• Sensitive: Light Sensitive
• BRN: 119302
• Cosmetics Ingredients Functions: PLASTICISER
• InChI: 1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2
• InChIKey: XLPJNCYCZORXHG-UHFFFAOYSA-N
• SMILES: C=CC(=O)N1CCOCC1
• LogP: -0.46 at 20.5-21℃
• CAS DataBase Reference: 5117-12-4(CAS DataBase Reference)
• NIST Chemistry Reference: N-acryloylmorpholine(5117-12-4)
• EPA Substance Registry System: Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4)

Description and Uses

4-Acryloylmorpholine (4-AM) is a water-soluble monomer, an acrylamide derivative containing a heterocyclic tetrahydrooxazine substituent. Homo- and copolymers of 4-АМ have several valuable properties. They are soluble both in water and in many organic solvents such as alcohols, chloroform, tetrahydrofuran, and dioxane, are non-toxic, and are used for solid-phase synthesis of peptides in chromatography, as materials for composite semipermeable membranes, in catalysis, and for biomedical purposes. Various functional groups are introduced into poly-4-AM to expand its application fields. Random copolymers of 4-АМ with carboxylic acids (acrylic, 4-pentenoic, undecenoic, 2-acrylamido-2-methyl-1-propanesulfonic), behaving as anionic polyelectrolytes, and copolymers with N-hydroxysuccinimide ester of acrylic acid, acting as polymeric carriers, have been synthesized[2-3].

4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.

Safety

• Symbol(GHS): GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H302-H317-H318-H373
• Precautionary statements: P280-P305+P351+P338
• PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
• Hazard Codes: Xn
• Risk Statements: 22-41-43-48/22
• Safety Statements: 23-26-36/37/39
• WGK Germany: 2
• TSCA: TSCA listed
• HS Code: 29349990
• Storage Class: 10 - Combustible liquids
• Hazard Classifications: Acute Tox. 4 Oral; Eye Dam. 1; Skin Sens. 1; STOT RE 2 Oral
• REACH Registrations: Active