Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) , 98% , 1375477-29-4

Synonym(s):
cataCXium A-Pd-G2;Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)

CAS NO.：1375477-29-4

Empirical Formula: C36H49ClNPPd

Molecular Weight: 668.64

MDL number: MFCD22200549

PRODUCT Properties

• Melting point: 220°C (decomposition)
• storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• form: solid
• InChIKey: ACPPOLPZSAKAJG-UHFFFAOYSA-N
• SMILES: P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)CCCC

Description and Uses

Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3