Home Categories (R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chlorideCatalyticreagent
BD0610153

(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chlorideCatalyticreagent , 98% , 164931-83-3

CAS NO.:164931-83-3

Empirical Formula: C36H52ClCrN2O2

Molecular Weight: 632.27

MDL number: MFCD02684555

EINECS: 605-379-1

Pack Size Price Stock Quantity
250mg RMB135.20 In Stock
1g RMB378.40 In Stock
5g RMB1472.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: >350 °C(lit.)
storage temp.  2-8°C, protect from light, stored under nitrogen
form  Powder
color  brown
InChIKey ZWANLSXDTHQDNO-OHRASPNLSA-K
SMILES CC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Cr](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C

Description and Uses

Catalyst used for:

  • Asymmetric anti-Mannich reactions
  • Coupling reactions
  • Ring-opening and Diels-Alder reactions
  • Allylic C-H oxidation of terminal alkenes

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn
Risk Statements  20/21/22
Safety Statements  26-36
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral

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