Home Categories (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate
(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate
SDS-US
BD2701145

(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate , 98% , 864943-22-6

Synonym(s):
(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

CAS NO.：864943-22-6

Empirical Formula: C48H29O4P

Molecular Weight: 700.72

MDL number: MFCD12546016

Pack Size Price Stock Quantity
100mg RMB487.20 In Stock
250mg RMB1000.80 In Stock
1g RMB2887.20 In Stock
5g RMB10128.80 In Stock
others     Enquire
Update time: 2022-07-08

PRODUCT Properties

Melting point: 390-400°C
Density  1.46±0.1 g/cm3(Predicted)
storage temp.  -20°C
form  solid
pka 1.11±0.20(Predicted)
Appearance White to off-white Solid
optical activity [α]22/D 44.0°, c = 1 in DMSO
InChIKey BVICVEIKBNVROI-UHFFFAOYSA-N
CAS DataBase Reference 864943-22-6

Description and Uses

Catalyst for:

  • Asymmetric hydrogenation cascade
  • Enantioselective Friedel-Crafts reaction
  • Asymmetric hydrogenation of 2-substituted quinolines
  • Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
  • Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
  • Asymmetric transfer hydrogenation of substituted quinoxalines

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315
Precautionary statements  P264-P280-P302+P352-P332+P313-P362+P364
WGK Germany  3
HS Code  2919900090

RELATED PRODUCTS

(11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(R)-3,3'-Bis(9-anthracenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthylHydrogenPhosphate
(R)-3,3'-Bis(9-anthracenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthylHydrogenPhosphate
1011465-29-4
(R)-3,3'-Bis[4-(trifluoromethyl)phenyl]-[1,1'-binaphthalene]-2,2'-diol
(R)-3,3'-Bis[4-(trifluoromethyl)phenyl]-[1,1'-binaphthalene]-2,2'-diol
791616-58-5

695162-86-8
(R)-(+)-2-Amino-2'-hydroxy-1,1'-binaphthyl
(R)-(+)-2-Amino-2'-hydroxy-1,1'-binaphthyl
137848-28-3