Home Categories (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate
(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate
SDS-US
BD3364551

(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate , 98%99%ee , 791616-62-1

CAS NO.：791616-62-1

Empirical Formula: C36H17F12O4P

Molecular Weight: 772.47

MDL number: MFCD08689863

Pack Size Price Stock Quantity
100mg RMB384.00 In Stock
250mg RMB779.20 In Stock
1g RMB2356.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 162-175 °C
Boiling point: 722.1±70.0 °C(Predicted)
Density  1.63±0.1 g/cm3(Predicted)
storage temp.  2-8°C
form  Powder
pka 1.09±0.20(Predicted)
color  white to light-yellow
optical activity [α]20/D -220°, c = 1 in chloroform (typical)
InChIKey DQORDVSQWPKAQJ-UHFFFAOYSA-N
SMILES O1C2=C(C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)C=C3C(=C2C2=C4C(C=CC=C4)=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C2OP1(=O)O)C=CC=C3

Description and Uses

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
HS Code  29319090

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