(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate , 99+% , 64536-78-3

Synonym(s):
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF₆;[Ir(cod)(PCy₃)(py)]PF₆;[Ir(cod)(PCy3)(py)]PF6;Crabtree’s catalyst;Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex

CAS NO.：64536-78-3

Empirical Formula: C31H47F6IrNP2

Molecular Weight: 801.88

MDL number: MFCD00075097

PRODUCT Properties

• Melting point: 175 °C (dec.)(lit.)
• Density: 1.67 g/cm3
• storage temp.: Inert atmosphere,Room Temperature
• solubility: Chloroform (Slightly)
• form: Crystalline Powder
• color: Orange
• Water Solubility: Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
• Sensitive: Moisture Sensitive
• Merck: 13,2594
• InChIKey: FGUUESBBRSXAAN-UHFFFAOYSA-O
• SMILES: [P+5]([F-])([F-])([F-])([F-])([F-])[F-].P(C1CCCCC1)(C1CCCCC1)(C1CCCCC1)[Ir+]123(N4=CC=CC=C4)C4CCC1=C2CCC3=4

Description and Uses

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: Xi,Xn
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 10-21
• TSCA: No
• HS Code: 29310099