Lithium acetylide ethylenediamine complex , tech.90 , 6867-30-7

CAS NO.：6867-30-7

Empirical Formula: C4H7LiN2

Molecular Weight: 90.05

MDL number: MFCD00013183

EINECS: 229-967-9

PRODUCT Properties

• Melting point: 76 °C (dec.)
• Boiling point: 110.6 °C (lit.)
• Density: 1,04 g/cm³
• Flash point: 7 °F
• storage temp.: 2-8°C
• solubility: Soluble in ethylene diamine, n-propyl amine, n-butyl amine, pyridine, dimethyl formamaide, diglyme, dioxan and dimethylsulfoxide.
• form: Crystals or Crystalline Powder
• color: Slightly yellow to light brownor
• Sensitive: Moisture Sensitive
• BRN: 3593824
• InChIKey: QJQWXTYPTBEPGS-UHFFFAOYSA-N
• CAS DataBase Reference: 6867-30-7(CAS DataBase Reference)
• EPA Substance Registry System: Lithium, (1,2-ethanediamine-.kappa.N,.kappa.N')ethynyl- (6867-30-7)

Description and Uses

• Lithium acetylide, ethylenediamine complex is a general reagent to synthesize ethynylated ketones.
• It is used as a ligand in the coordination chemistry to synthesize transition metal complexes such as 1-alkynyl-dimethyl(triorganophosphine)gold(III) complex.
• It is employed in the ring opening reaction of epoxides, as in the total synthesis of (?)-goniotrionin and englerin A.
• It can also be used in the ethynylation of alkyl halides to prepare terminal alkynes.

Safety

• Symbol(GHS): GHS02,GHS05
• Signal word: Danger
• Hazard statements: H261-H314
• Precautionary statements: P231+P232-P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310
• Hazard Codes: F,C
• Risk Statements: 15-34-67-65-63-48/20-11-35-14/15-20/21/22-14
• Safety Statements: 26-43-45-62-36/37/39-43B-16-6A-7/8-3/7/9
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 3
• F: 10-21
• TSCA: Yes
• HazardClass: 4.3
• PackingGroup: III
• HS Code: 38249095
• Limited Quantities: 0.5 Kg (1.1 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)