Isopropylmagnesium chloride - LiCl complex , Null , 807329-97-1

Synonym(s):
Turbo Grignard

CAS NO.：807329-97-1

Empirical Formula: C3H7Cl2LiMg

Molecular Weight: 145.24

MDL number: MFCD07784514

PRODUCT Properties

• Boiling point: 66℃
• Density: 0.951 g/mL at 25 °C
• Flash point: -17 °C
• solubility: Miscible with ethers and amines.
• Sensitive: Air & Moisture Sensitive
• InChI: 1S/C3H7.2ClH.Li.Mg/c1-3-2;;;;/h3H,1-2H3;2*1H;;/q;;;2*+1/p-2
• InChIKey: CWTUREABAILGIK-UHFFFAOYSA-L
• SMILES: [Li]Cl.CC(C)[Mg]Cl

Description and Uses

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Safety

• Symbol(GHS): GHS02,GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H302-H333-H335-H351-H225-H261-H314-H318
• Precautionary statements: P210-P223-P303+P361+P353-P305+P351+P338-P405-P501a
• target organs: Central nervous system, Respiratory system
• PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• Hazard Codes: F,C
• Risk Statements: 14/15-19-34-11
• Safety Statements: 16-26-29-33-36/37/39-43-45-8
• RIDADR: UN 3399 4.3/PG 2
• WGK Germany: WGK 3
• HazardClass: 4.3
• HS Code: 29319090
• Storage Class: 3 - Flammable liquids
• Hazard Classifications: Carc. 2; Eye Dam. 1; Flam. Liq. 2; Skin Corr. 1B; STOT SE 3