Thallium(III) acetate hydrate , Null , 2570-63-0

Synonym(s):
thallic acetate;Tl(OAc)3;tris(acetate)thallium

CAS NO.：2570-63-0

Empirical Formula: C2H5O2Tl

Molecular Weight: 265.44

MDL number: MFCD00008698

EINECS: 219-913-2

PRODUCT Properties

• Melting point: 182 °C (dec.)(lit.)
• storage temp.: Poison room
• solubility: sol hot acetic acid, alcohols, H2O.
• form: Crystalline Powder
• color: White to off-white
• BRN: 3693590
• InChI: 1S/3C2H4O2.Tl/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
• InChIKey: SMRRYUGQTFYZGD-UHFFFAOYSA-K
• SMILES: [TlH].CC(O)=O
• CAS DataBase Reference: 2570-63-0(CAS DataBase Reference)
• EPA Substance Registry System: Acetic acid, thallium(3+) salt (2570-63-0)

Description and Uses

Thallium(III) Acetate is used for oxidation of alkenes and alkynes; oxidation of conjugated dienes; hydroxylation of double bonds; cleavage of cyclopropane rings; oxidation of enamines; oxidative rearrangements; bromination of aromatic compounds; oxidation of thiols and p-toluenesulfonylhydrazones; formation of acyloxy carboxylic acids; oxidative cyclizations.

Safety

• Symbol(GHS): GHS06,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H300+H330-H373-H411
• Precautionary statements: P260-P264-P273-P284-P301+P310-P310
• PPE: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• Hazard Codes: T+,N
• Risk Statements: 26/28-33-51/53-26/27/28
• Safety Statements: 13-28-45-61-36/37/39-22
• RIDADR: UN 1707 6.1/PG 2
• WGK Germany: 3
• TSCA: TSCA listed
• HazardClass: 6.1
• PackingGroup: II
• HS Code: 29152900
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2; very toxic hazardous materials
• Hazard Classifications: Acute Tox. 2 Inhalation; Acute Tox. 2 Oral; Aquatic Chronic 2; STOT RE 2
• Limited Quantities: 100ml (liquid) or 0.5 Kg (solid)
• Excepted Quantities: Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)