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S159379

Woollins’ Reagent , 122039-27-4

CAS NO.:122039-27-4

Empirical Formula: C12H10P2Se4

Molecular Weight: 532

MDL number: MFCD04041197

Pack Size Price Stock Quantity
1g RMB654.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 206-210 °C (lit.)
Boiling point: 530.8±33.0 °C(Predicted)
storage temp.  2-8°C
form  solid
InChI 1S/C12H10P2Se4/c15-13(11-7-3-1-4-8-11)17-14(16,18-13)12-9-5-2-6-10-12/h1-10H
InChIKey GKYFQRQKPYPLGJ-UHFFFAOYSA-N
SMILES [Se]=P1([Se]P(=[Se])([Se]1)c2ccccc2)c3ccccc3

Description and Uses

Reagent involved in reactions with:

  • Benzoic hydrazides to yield spiro heterocycles
  • Secondary amines
  • Aromatic diols to yield 10-membered phosphorus-selenium heterocycles

Reagent involved in ring-opening, deselenation and phosphorus-phosphorus coupling

Safety

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H331-H315-H335-H373-H410
Precautionary statements  P260-P273-P301+P310-P302+P352-P304+P340+P311-P314
target organs Respiratory system
Hazard Codes  T,N
Risk Statements  23/25-33-50/53
Safety Statements  20/21-28-45-60-61
RIDADR  UN 3283 6.1/PG 3
WGK Germany  3
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Skin Irrit. 2
STOT RE 2
STOT SE 3