9-BBN triflate solution , 0.5?Minhexanes , 62731-43-5

Synonym(s):
9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane;9-BBN triflate solution;9-BBN·CF3SO3;9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution

CAS NO.：62731-43-5

Empirical Formula: C9H14BF3O3S

Molecular Weight: 270.07

MDL number: MFCD00167981

PRODUCT Properties

• Boiling point: 265.7±50.0 °C(Predicted)
• Density: 0.733 g/mL at 25 °C
• Flash point: -22 °C
• solubility: sol common inert organic solvents such as Et2O, CH2Cl2, and hexane.
• form: liquid
• BRN: 995656
• InChI: 1S/C9H14BF3O3S/c11-9(12,13)17(14,15)16-10-7-3-1-4-8(10)6-2-5-7/h7-8H,1-6H2/t7-,8+
• InChIKey: NXHUKDCGEGEZCX-OCAPTIKFSA-N
• SMILES: FC(F)(F)S(=O)(=O)OB1C2CCCC1CCC2

Description and Uses

Reactant for:

• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
• Mukaiyama aldol addition
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
• Preparation of palladium porphyrin complexes
• Boron-mediated β-alkoxy Me ketone aldol addition reactions

• Enolization agent

Safety

• Symbol(GHS): GHS02,GHS07,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H225-H304-H315-H336-H361f-H373-H411
• Precautionary statements: P201-P210-P273-P301+P310-P308+P313-P331
• target organs: Central nervous system, Nervous system
• PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
• Hazard Codes: F,C,N,Xn
• Risk Statements: 11-34-48/20-51/53-62-65-67-38
• Safety Statements: 16-26-36/37/39-45-61-62-36/37
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 3
• F: 1-10
• HS Code: 29349990
• Storage Class: 3 - Flammable liquids
• Hazard Classifications: Aquatic Chronic 2; Asp. Tox. 1; Eye Irrit. 2; Flam. Liq. 2; Repr. 2; Skin Irrit. 2; STOT RE 1 Inhalation; STOT SE 3