S492279
Manganese(II) chloride bis(lithium chloride) complex solution , density:0.956 g/mL at25 °C,0.5 MinTHF , 57384-24-4
Synonym(s):
Lithium chloromanganate(II);Lithium manganese chloride;Lithium tetrachloromanganate(II) solution;Manganese(II) chloride bis(lithium chloride) complex solution
| Pack Size | Price | Stock | Quantity |
| 100ml | RMB1080.88 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 67 °C |
| Density | 0.976 g/mL at 25 °C |
| Flash point: | −2 °F |
| form | liquid |
| InChI | 1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4 |
| InChIKey | VJOUQNFWQPCDPE-UHFFFAOYSA-J |
| SMILES | [Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl |
Description and Uses
Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant
Reactant for:
- Transmetalation reactions
- Nickel-imidazolium carbene-catalyzed coupling reactions
Reagent for the preparation of Rieke manganese
Safety
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H302-H315-H319-H335-H351 |
| Precautionary statements | P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235 |
| target organs | Respiratory system |
| Hazard Codes | F,Xn |
| Risk Statements | 11-19-22-36/37/38-40-36/37 |
| Safety Statements | 16-26-33-36-36/37 |
| RIDADR | UN 1993 3/PG 2 |
| WGK Germany | 3 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Acute Tox. 4 Oral Carc. 2 Eye Irrit. 2 Flam. Liq. 2 Skin Irrit. 2 STOT SE 3 |
