1375325-64-6

Synonym(s):
2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II);SPhos-Pd-G2

CAS NO.：1375325-64-6

Empirical Formula: C38H44ClNO2PPd+

Molecular Weight: 719.608

MDL number: MFCD20264897

PRODUCT Properties

• Melting point: 218°C (dec.)
• storage temp.: 2-8°C, protect from light, stored under nitrogen
• form: Powder
• color: white
• InChIKey: PYMQIHHZINPLDV-UHFFFAOYSA-N
• SMILES: P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

Description and Uses

Application in Suzuki-Miyaura coupling:

• Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
• Suzuki–Miyaura coupling of [Ru(bpy)₂]⁺ with 4-carboxyphenylboronic acid.
• Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

Safety

• WGK Germany: 3