Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV) , 97% , 100163-29-9

Synonym(s):
Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium

CAS NO.：100163-29-9

Empirical Formula: C20H24Cl2Zr10*

Molecular Weight: 426.53

MDL number: MFCD00672123

PRODUCT Properties

• Melting point: 267-271 °C(lit.)
• form: Powder
• color: white to pale yellow
• Sensitive: moisture sensitive
• InChI: InChI=1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
• InChIKey: AKXWJOYQORUUHS-UHFFFAOYSA-L
• SMILES: [C]12[C]([CH][CH][C]1CCCC2)CC[C]1[CH][CH][C]2CCCC[C]12.[Zr](Cl)Cl |^1:0,1,2,3,4,11,12,13,14,19|

Description and Uses

Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: C,Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-36/37/39-45-36
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3